Ukuthengisa Okushisayo Nekhwalithi Ephezulu I-Cesium Carbonate CAS 534-17-8 enenani Elihle

I-PrIzakhiwo eziningi ze-cesium carbonate ku-organic synthesis zithathwe ku-acidity ye-Lewis ethambile ye-cesium ion, eyenza inyibilike kuzincibilikisi zemvelo ezifana notshwala, i-DMF ne-ether.Ukunyibilika okungcono kwezinyibilikisi eziphilayo kwenza i-cesium carbonate ibambe iqhaza ekuphenduleni kwamakhemikhali okubangelwa ama-reagents e-palladium njengesisekelo esisebenzayo sezinto ezingaphili, ezifana nokusabela kwe-Heck, i-Suzuki ne-Sonogashira.Isibonelo, ukusabela kwe-Suzuki cross coupling ne-cesium carbonate kwakwazi ukuthola isivuno esingu-86%, kuyilapho ukusabela okufanayo nge-sodium carbonate noma i-triethylamine kwaba kuphela ama-29% kanye nama-50%.Ngokufanayo, ekuphenduleni kwe-Heck ye-methacrylate ne-chlorobenzene, i-cesium carbonate uma iqhathaniswa nezinye izisekelo ze-inorganic, njenge-potassium carbonate, i-sodium acetate, i-triethylamine, i-potassium phosphate, ibonise inzuzo esobala kakhulu.I-Cesium carbonate nayo inezinhlelo zokusebenza ezibalulekile ku-o-alkylation yama-phenol compounds.Kucatshangelwa ukuthi ukusabela kwe-phenol O-alkylation ku-cesium carbonate non-aqueous solvent kungenzeka kube ne-phenoxyethylene anion, ngakho-ke ukusabela kwe-alkylation kungase kwenzeke kuma-halogenates esibili anomsebenzi ophezulu kanye nokusabela okulula kokuqeda.I-Cesium carbonate nayo inezinhlelo zokusebenza ezibalulekile ekuhlanganiseni imikhiqizo yemvelo.Isibonelo, ekuhlanganiseni kwe-Lipogrammistin-inhlanganisela ku-A key step-close-loop reaction, i-cesium carbonate njengesisekelo se-inorganic ingasetshenziswa ukuthola imikhiqizo evaliwe ene-loop ephezulu.Ngaphezu kwalokho, i-cesium carbonate inezinhlelo zokusebenza ezibalulekile ekuphenduleni okuqinile okusekelwa kwe-organic ngenxa yokuncibilika kwayo okuhle kuzinyibilikisi zemvelo.I-Carboxylate noma i-carbamate compounds ingahlanganiswa ngesivuno esiphezulu ngokudala ukusabela kwezingxenye ezintathu ze-aniline nge-halogen eqinile esekelwe emoyeni we-carbon dioxide.Ngaphansi kwe-microwave irradiation, i-cesium carbonate ingasetshenziswa njengesisekelo sokubona ukusabela kwe-esterification phakathi kwe-benzoic acid nama-halogenates asekelwe aqinile.